No, the Rode NT-USB Mini is not compatible with the TC-Helicon GoXLR.
Rode NT-USB Mini is a USB condenser microphone that connects to a computer via USB. GoXLR's only microphone input is a single balanced XLR connector. USB microphones cannot provide audio through GoXLR's signal chain.
What works instead
See all compatible microphone for the Rode NT-USB Mini →“At a glance comparison table: GoXLR has 1 XLR input (Max mic gain ~72 dB); Wave XLR Pro successor has 2 XLR inputs (80 dB). GoXLR's real, current spec is 1 XLR input.”
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