No, the Fujifilm X100VI is not compatible with the ProGrade Digital CFexpress Type A 120GB.
Fujifilm X100VI has an SD-only card slot (no CFexpress support of any type). Its own product page confirms only SD/SDHC/SDXC card compatibility -- CFexpress Type A uses a physically different connector and cannot be inserted into an SD slot.
What works instead
See all compatible camera for the Fujifilm X100VI →“Storage Media SD Card (-2GB) SDHC Card (-32GB) SDXC Card (-2TB) UHS-I”
Last verified:
Compatibility inferred from spec rule (citations above are manufacturer-verified)